2003 Archived News

30 December 2003:  Green Chemistry Summer School
29 December 2003:  UNC Black Enrollment Praised
10 December 2003:  Luke Zannoni Defense Pictures
05 December 2003"Totally 'Green' Nanoparticle Synthesis"
04 December 2003:  Green Engineering
03 December 2003Green Engineering
01 December 2003:  "Some Shops Offer a New Kind of Clean"
11 November 2003:  UNC Covenant Creating Ripples
10 November 2003:  UNC-Chapel Hill breaks new ground in college accessibility
03 November 2003:  2003 Conference on K-12 Outreach
27 October 2003:  193 Nanometer Stepper
22 October 2003:  Kiplinger Ranks CERSP Schools Highly
21 October 2003:  ACS Symposium on Polymers
20 October 2003:  A New Post-Doc Position at NC A&T
16 October 2003:  Boss's Day Celebration
11 October 2003:  Karen Kennedy's Defense Pictures
10 October 2003:  Executive Summary 2003 Annual Report
09 October 2003:  Lithography Center Website
08 October 2003:  CERSP Newsletter
17 September 2003:  ACS Pictures from NY 
09 September 2003:  Dr. Joseph DeSimone featured on NCSU's College of Engineering Achieve! website
08 September 2003:  "UNC Innovations Assist Companies" article from UNC's The Daily TarHeel
02 September 2003:  U of Arizona - MIT - Stanford - UC-Berkeley ERC Retreat Presentations
10 August 2003:  Professor Royce Murray Honored (Again!)
04 August 2003:  The Special Hour: Rollie Tilman Interview of Dr. Joseph DeSimone
03 August 2003:  "Cool & Clean" article from the Star Tribune
22 July 2003:  "Teachers Go to Summer Class:  Workshop to Benefit Students in Fall Science Courses" article from the Greensboro News & Record
10 July 2003:  Comprehensive CO2 Phase Data
22 June 2003: Jennifer Kelly is Home!
22 June 2003:  "Plastic Recyling Process Overcomes Contamination Problems"  from CEP Magazine
03 June 2003:  CERSP Schools Rated in Top 25
02 June 2003:  Welcome to Russ Osmond and SPSU
28 May 2003:  EYH Highlighted on NC Now
27 May 2003:   Johnston Elected VP of International SCF Society
22 May 2003:  Teflon® Fluoropolymers with High Transparency on Display in Frankfurt
15 May 2003:  Carbonell Speaks on STC Impact
07 May 2003:  "Clean Equals Green" article from Electronic Business
06 May 2003:  SuccessToday - Interview with Dr. Joseph M. DeSimone, Distinguished Professor
05 May 2003:  New Teflon Process Not Widely Used at DuPont
30 April 2003:  Brookhart Receives Polymer Award
29 April 2003:   Shah Wins 2003 Celanese Competition
21 April 2003:  CO2 Process to Recycle Plastic Bottles
28 March 2003:  Spring Review Agenda
25 March 2003:  Jay Simhan Receives  Rand Scholarship
22 March 2003:  UNC's Charles Jones Receives Fellowship
10 March 2003:  Mentoring Seminar at NC State
06 March 2003:  Solid State NMR Tutorial
26 February 2003:  Ed Samulski Video from WRAL-TV5 News
14 February 03:  Joe DeSimone's letter-to-the-editor featured in The News & Observer
06 February 03: "Supercritical CO2 Cleaning Enables Sub-65 nm Processing" from Semiconductor International
10 March 2003:  Mentoring Seminar at NC State
17 January 03:  UNC-CH 15TH & NCA&T 19TH for Black Students
13 January 03: Safety Alert from UNC-CH Chemistry Department
03 January 03:  Microchips' Heavy Burden article in Chemical & Engineering News
02 January 03:  BOC Edwards & Micell Integrated Systems to Jointly Commercialize Supercritical CO2 Systems & Process Technology

30 December 2003:  Green Chemistry Summer School
   
     The American Chemical Society Petroleum Research Fund (ACS-PRF) is sponsoring a Summer School on Green Chemistry at Carnegie-Mellon University in Pittsburgh, PA July 31 – August 7, 2004. For details click here

29 December 2003:  UNC Black Enrollment Praised
   
     Once again, UNC-CH had the highest percentage of black enrollment among highly ranked universities around the nation, according to the Journal of Blacks in Higher Education.  Blacks make up 11.1 percent of the student body at Chapel Hill, the highest percentage of black students among the nation's 50 highest-ranked universities.  In this year's freshman class at Chapel Hill, blacks make up 11.7 percent of all entering students.  For details click here.

10 December 2003:  Luke Zannoni Defense Pictures (click on image to enlarge)

05 December 2003"Totally 'Green' Nanoparticle Synthesis" article in Chemical & Engineering News profiles the work of UNC's Assistant Professor of Chemistry Scott L. Wallen and coworkers Poovathinthodiyil Raveendran and Jie Fu.

04 December 2003:  Green Engineering
   
     The principles of Green Engineering are laid out in the outline of this course to be presented Spring 2004 semester from the University of Delaware. Click here for the course outline.

03 December 2003:  Green Engineering
CHEG 667-015
Spring 2004
Mon, Wed 5-6:15 pm
Professor Richard P. Wool

Course Description:
"Green engineering is the design, commercialization, and use of processes and products, which are feasible and economical while minimizing 1) generation of pollution at the source and 2) risk to human health and the environment. The discipline embraces the concept that decisions to protect human health and the environment can have the greatest impact and cost effectiveness when applied early to the design and development phase of a process or product." (EPA, 2003). 

Green Engineering transforms existing engineering disciplines and practices to those that promote sustainability.  Green Engineering incorporates development and implementation of technologically and economically viable products, processes and systems that promote human welfare while protecting human health and elevating the protection of the biosphere as a criterion in engineering solutions.

To fully implement green engineering solutions, engineers use the following principles:

1.                  Engineer processes and products holistically, use systems analysis, and integrate environmental impact assessment tools.

2.                  Conserve and improve natural ecosystems while protecting human health and well-being.

3.                  Use life cycle thinking in all engineering activities.

4.                  Ensure that all material and energy inputs and outputs are as inherently safe and benign as possible. 

5.                  Minimize depletion of natural resources. 

6.                  Strive to prevent waste.

7.                  Develop and apply engineering solutions, while being cognizant of local geography, aspirations and cultures.

8.                  Create engineering solutions beyond current or dominant technologies; improve, innovate and invent (technologies) to achieve sustainability.

9.                  Actively engage communities and stakeholders in development of engineering solutions

This course takes a multidisciplinary, problem solving approach, to developing the necessary tools and applying the principles of Green Engineering to analyze and address real world problems. 

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01 December 2003:  "Some Shops Offer a New Kind of Clean" article from the Washington Post
        Article covers how a shop owner has switched from using perchloroethylene as their standard solvent to the cutting-edge liquid carbon-dioxide cleaning method in an effort to be more environmentally safe and health-conscious.

11 November 2003:  UNC COVENANT CREATING RIPPLES
        A new financial aid program has been introduced at the University of North Carolina-Chapel Hill under which low-income students will have all their financial aid needs met through grants instead of loans.
        Shirley Ott, director of scholarships and student aid at Chapel Hill , reports that 11 states have inquired about the program since the announcement. She has been in contact with officials in California, Georgia, Kentucky, Maine, Michigan, Missouri, Nebraska, New York, Virginia, Washington and Wisconsin.
        Virginia
appears to be the most interested. John Casteen III, president of the University of Virginia, ordered his staff to prepare a report showing whether his university could implement a similar plan.
        For details of the Carolina Covenant click here.

10 November 2003:  UNC-Chapel Hill breaks new ground in college accessibility
CHAPEL HILL , N.C. -- University of North Carolina at Chapel Hill Chancellor James Moeser has announced a groundbreaking initiative to give the children of low-income families an opportunity to attend college – without borrowing a penny.

The Carolina Covenant will enable low-income students to come to Carolina and graduate debt-free if they work on campus 10 to 12 hours weekly in a federal work-study job throughout their four years here, instead of borrowing. The university will meet the rest of students’ needs through a combination of federal, state, university and private grants and scholarships.

Carolina already meets 100 percent of the documented financial need of all students who apply for aid on time, but about a third of that need is being met through loans. To fund the Carolina Covenant, the university will make modest reallocations of existing funds in the Office of Scholarships and Student Aid and pledge growing private gifts dedicated to low-income students. The initiative is expected to cost about $1.38 million annually when fully phased in four years from now.

Carolina is believed to be the first public university in America to launch such an initiative to make college more accessible. Princeton , a private university, has also done much to alleviate the need for student borrowing.

The Carolina Covenant will go into effect next fall for the incoming freshman class of 2004. Eligible students must be at or below 150 percent of the federal poverty level. Under current federal poverty levels, a family of four with an annual income of about $28,000 would qualify. For a single parent with one child, the eligible income would be about $18,000.

Moeser announced the innovative access initiative in his annual State of the University speech to the campus community Oct. 1. "College should be possible for everyone who can make the grade, regardless of family income," he said. "A covenant is a promise. With the Carolina Covenant, we are telling students that, despite what you may see in the news, college is affordable, no matter how much money your family makes."

Moeser credited Shirley Ort, associate provost and director of scholarships and student aid, and Jerry Lucido, vice provost for enrollment management and director of undergraduate admissions, for their vision in crafting this new initiative.

"We know that too many prospective students – especially first-generation students – may not be pursuing the opportunity because they don’t think their families can afford college," Ort said. "This initiative will help reverse that trend."

Studies show that the cost of college is rising steadily for low-income families. Nationally, the average student loan debt has nearly doubled to $17,000 over the past decade. About one-fifth of full-time students work 35 or more hours a week. As a result, many low-income youth abandon plans for college – or drop out – because the burden of that debt and workload is too much. The patterns are even stronger among minority students, experts say. Research also shows that low-income families need more information – and greater predictability – about the availability of financial aid.

Moeser cited the state of the economy and the rising number of families living in poverty as evidence of the need for the Carolina Covenant. Since one in four North Carolina children now live in poverty, the need for an accessibility initiative like the Carolina Covenant will remain strong, Moeser said. According to the N.C. Children’s Index of 2002, more than one-third of North Carolina’s families made less than $28,000 a year in 1999, the last year data were available.

This fall, 281 of UNC-Chapel Hill’s freshmen – 8 percent of the freshman class – came from low-income families. Most of those – 89 percent – were from North Carolina .  More than half were minorities. Federal and state financial aid covered about 60 percent of the college costs of those students.

The Carolina Covenant will supplement the university’s long-standing program of providing generous financial assistance to needy students and need-blind admissions, referring to the practice of granting admission to qualified applicants without consideration of their family’s ability to pay.

UNC-Chapel Hill has worked hard to bring low-income students to campus, Lucido said. In the last three years, the number of low-income students enrolling as freshmen rose by 20 percent. In recent years, when the university enacted a campus-based tuition increase, it dedicated 35 percent of the receipts to aid for needy students, and every needy student received a grant to cover any campus-based tuition increase.

But that’s not enough, Moeser said. "As the first public university in America , Carolina has always been committed to access," he said. "With the Carolina Covenant, we are strengthening our commitment to ensure that families from all income levels can afford a Carolina education."

The Carolina Covenant is the second major national initiative UNC-Chapel Hill has launched to benefit students. Starting with freshmen applying for admission this fall, UNC became the nation’s first major American public university to eliminate its binding early decision admissions plan.

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03 November 2003:  2003 Conference on K-12 Outreach
   
     The Proceedings of the Conference on K-12 Outreach from University Science Departments are now posted in pdf format on The Science House website. Click here to access.

27 October 2003:  193 Nanometer Stepper
    The 193 Nanometer Stepper has arrived at North Carolina State University; installation will take place over the next 2 weeks.  Read the story at NCSU's BulletinOnline and click on the below thumbnails for pictures:
22 October 2003:  Kiplinger Ranks CERSP Schools Highly
   
     The current issue of Kiplinger's contains the magazine's annual listing of "The 100 Best Values in Public Colleges." All of CERSP Research I universities rank in the top twenty best values among public colleges. The rankings are based on data submitted by 500 public colleges and universities nationwide. Academic criteria such as selectivity, graduation rate, student-faculty ratios, library resources, and funds spent per student make up two thirds of an institution's score. Cost factors account for one third of an institution's ranking. "The formula places greater weight on quality than cost," Kiplinger's says, "because 'value' is not synonymous with cheap." Leading the list for the fourth consecutive year is the University of North Carolina at Chapel Hill. In addition to UNC-CH at #1, Georgia Tech ranks #7; NC State, #11; and the University of Texas-Austin, #20.  For details click here.

21 October 2003:  ACS Symposium on Polymers
   
     A symposium on polymers with strong emphasis on CO2 has been announced for March 28-April 1, 2004 in Anaheim, CA. Abstracts are due November 30, 2003. For details click here.

20 October 2003:  A New Post-Doc Position at NC A&T (position has been filled)
    A new post-doctoral position has been defined at NC A&T.  Click here for the position description. 
    The position is expected to be filled by June 2004 and will be responsible for implementing the program described here. 

16 October 2003:  Boss's Day Celebration (click image to enlarge)
 

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11 October 2003:  Karen Kennedy's Defense (click image to enlarge)
10 October 2003:  Executive Summary 2003 Annual Report
   
     CERSP 2003 Annual Report is online. For the complete report, click 2003 Annual Report on the homepage. For an executive summary summary click here.

09 October 2003:  Lithography Center Website
   
     Click here to reach the Triangle National Lithography Center website.   TNLC is closely affiliated with CERSP.

08 October 2003:  CERSP Newsletter
   
     The most recent CERSP newletter has issued. For a hardcopy, contact Dr. Darlene Taylor at dkt@unc.edu 

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17 September 2003:  ACS Pictures from NY (click image to enlarge)


02 September 2003:  U of Arizona - MIT - Stanford - UC-Berkeley ERC Retreat Presentations
Strategic EHS Considerations in Selections of Next Generation Fab Materials
Growth of Planarized Copper Films by Electrochemical Mechanical Deposition (ECMD) Technique
CMP Comsumable Technologies in PERL HITACHI
Effects of Electrochemical Deposition Process Conditions on CMP
Thermal Modeling for Oxide & Copper Polishing
Slurry-Free, Pad-Free & Stress-Free Cu Polishing for Cu Integrated w/ Low k & Ultra Low k Dielectrics
Single Asperity Studies of Tribochemical Wear
Roadmap for New Materials:  Critical Drivers & Issues
Si-Ge-C MOS Technology
Novel 1-d Nanostructures for Device Fabrication
3-D Interconnects Using Cu Wafer Bonding: Technology & Applications
Device Structures & Materials for Scaling to Si Limits & Beyond
Manufacturing, The Environment & the Business Case:  A Systems Perspective
Risk Management & Lifestyle Assessment
Overview of Dual Damascene Cu/Low-k Interconnect
Supercritical CO2 Tools & Applications for Semiconductor Processing
NSFSTC
Post Ash & Post Etch Cleaning using SuperCritical CO2
Negative Tone, Chemically Amplified Resist Deviloped in CO2
k Value Restoration of Porous CDO Films using Supercritical Carbon Dioxide
New Chemistries & Tools for Supercritical CO2 Processing of Thin Films
Molecular Modeling Tutorial
Quantum Chemistry of Electronic Materials Processing

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10 August 2003:  Professor Royce Murray Honored (Again!)
        It was recently announced that the major quadrangle between the new Venable buildings and the Phillips Addition will be named the Royce Murray Quadrangle.

04 August 2003:  The Special Hour: Rollie Tilman
   
Joe DeSimone's audio interview from 18 June 2003 on WCHL 1360:
   
         Part 1 | Part 2 | Part 3 | Part 4 | Part 5

22 June 2003: Jennifer Kelly is Home!
        Most of you know that Jennifer Kelly, a first-year graduate student in Prof. DeSimone’s group, was critically injured in an automobile accident at 10:30 PM on June 3. Her car hit a tree and was totally demolished. She had to be cut from the wreckage. She was conscious and apparently, at the time, not badly hurt—just a small bruise on her forehead and shoulder. In fact, she had a very serious head injury. Two safety points:

1) seat belts probably saved her life
2) although outwardly okay, she was taken to the emergency room for examination. Initially, only a small amount of internal bleeding was detected; but a later test determined serious, life-threatening hemorrhaging in her brain

        After six hours of emergency surgery, she was out of danger but unable to speak or move her right side for several days. She has made remarkable progress and was released from rehab last Saturday, June 21. She is now at home in Maryland . She looks great, is walking and talking slowly, but still has some problems with her right arm. But she is as feisty as ever and already making plans to link to the UNC chemistry library so she can continue to work as she recovers. She can be reached at jykelly@email.unc.edu
        By the way, her first words on June 5 (spelled by pointing to letters on a board) were “How did the NSF review go?”

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03 June 2003:  CERSP Schools Rated in Top 25
   
     Technology Review, MIT's Magazine of Innovation, and CHI Research have published their University Research Scorecard 2002. In it all four CERSP Research I Universities scored in the top 25 among US colleges and universities. University of Texas-Austin was rated #6; UNC-Chapel Hill, #12: and NCSU and Georgia Tech tied at #22. 

02 June 2003:  Welcome to Russ Osmond and SPSU
   
     Welcome to Dr. Russ Osmond and Southeastern Polytechnic State University, new affiliates of CERSP. We have arranged with Dr. Russ Osmond to conduct a series of videoconference seminars.  These seminars will be conducted beginning fall 2003 and will be available to STC students on all CERSP campuses.  The seminar series is intended to improve students' collaborative and team-building skills, mainly through improved self-awareness and sensitivity to their own and others personal styles, strengths and weaknesses. Because collaboration among scientists/engineers of diverse backgrounds is such a key skill in our Center, Russ (adjunct faculty) and SPSU are being officially listed as CERSP "affiliates".  Southern Polytechnic is a co-educational member of the University System of Georgia, located on 232 wooded acres in Marietta, just outside Atlanta. To learn more about SPSU, click here.

28 May 2003:  EYH Highlighted on NC Now
        The “Expanding Your Horizons” story aired May 27on UNC-TV's “NC Now” program.  The focus of the program was the growing need for a workforce trained in high tech skills.  EYH is one of many programs aimed at building that future workforce.  The EYH program, run by the Science House and supported by CERSP and Burroughs Wellcome Fund among others, seeks to interest girls of middle school age (mostly 7th graders) in pursuing science as a career.  It was reported that over 700 girls from all over the state attended this year’s sessions.  The show featured many vignettes of girls enthusiastically examining laboratory experiments and excitedly talking with one another about DNA and other topics not normally covered in 7th grade.
        Two members of CERSP appeared prominently in the program.  Prof. David Haase, Director of Science House, described how Science House helps to enhance K-12 science education and thereby contributes to building NC’s economy.  Prof. Bob Kelly showed some of his laboratory facilities and described the great potential of biotech to provide growth opportunities for NC.
 

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27 May 2003:   Johnston Elected VP of International SCF Society
   
Congratulations to Prof. Keith Johnston on being elected Vice-president of the International Society for the Advancement of Supercritical Fluids. The election occurred at the annual meeting of the society, which took place during the 6th INTERNATIONAL SYMPOSIUM ON SUPERCRITICAL FLUIDS, held April 28-30, 2003 at Versailles (France). Prof. Johnston gave one of the plenary lectures at this meeting. For details on the Society, click here

15 May 2003: Carbonell Speaks on STC Impact
   
     Prof. Ruben Carbonell will be representing CERSP in two important venues during June.  He plans to address the NC Board of Science and Technology on June 13 on the topic of "Advancing Innovation in Traditional North Carolina Industries".  He will discuss how future of technology innovations may impact traditionally important North Carolina industries such as textiles, furniture, apparel, paper, tobacco, etc.  He will talk about CERSP and its role in dry cleaning, polymer synthesis, microelectronics, etc., and how it has to potential to bring new, “high tech” industries to NC.
       
NSF has invited Prof. Ruben Carbonell to participate in a trip to Lisbon , Portugal . The visit, scheduled for June 30 to July 4, is intended to help develop collaborations among research centers, industry and national laboratories in the U.S. and Portugal .  Prof. Carbonell plans to use CERSP as an example of best practices in this area.  

29 April 2003:   Shah Wins 2003 Celanese Competition
CERSP congratulates Parag Shah for winning the 2003 Celanese Competition for his talk “Single Step Synthesis of Ordered Macroporous Nanocrystal Thin Films.”  This is the top graduate student award given annually in the Chemical Engineering Department at UT-Austin.  To read an abstract of the talk, click here.  

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25 March 2003:  Jay Simhan Receives  Rand Scholarship
    The Undergraduate Studies Committee has awarded UNC's Jay Simhan one of the 2003 Emmett Gladstone Rand Premedical Scholarships in Chemistry. Congratulations on this honor.   William G. and Bettie Allison Rand established the Emmett Gladstone Rand Premedical Scholarship in Chemistry in 1984 in honor of his father, Emmett Gladstone Rand, M.D., B.A. '22, C. Med. '24. It is intended to honor exceptionally talented senior undergraduate students intending to pursue a career in medicine.  The award consists of a stipend and will be presented at the departmental graduation exercises on Commencement Day, May 18.

22 March 2003:  UNC's Charles Jones Receives Fellowship
        The National Organization for the Professional Advancement of Black Chemists & Chemical Engineers (NOBCChE) has awarded Charles Jones a graduate fellowship sponsored by The Dow Chemical Company.  It will be presented at the NOBCChE annual meeting at the Marriott Indianapolis Downtown Hotel in Indianapolis, IN on Thursday, 17 April 2003.

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06 March 2003:  Solid State NMR Tutorial
   
The UNC-CH NMR facility will present a solid state NMR tutorial beginning on April 7 and lasting 4 weeks. The format is : A 50 minute discussion will be held each Monday and a 3 hour hands-on session at the spectrometer each week on either Tuesday or Wednesday. The facility is offering this free of charge to interested students, post-docs and faculty.  We will cover:

*differences between high resolution liquids and solid state NMR
*information available from routine solid state NMR
*descriptions of some experiments
*instrumentation for solid state NMR
*setting up, running and processing the data

                If time is available, we can try some user samples. If interested, contact Marc ter Horst, by March 14th, with your UNC email address (onyen) and group affiliation. Also include your background in NMR and the kinds of samples or kinds of experiments you think you might be interested in.

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14 February 03:  Joe DeSimone's letter-to-the-editor featured in The News & Observer:
Feb. 12, 2003
The News & Observer
© Copyright 2003 The News & Observer Publishing Company.

Regarding the Feb. 10 article "State cleaning up after the cleaners": I trust you know that an environmentally friendly dry cleaning process based on carbon dioxide was developed right here in North Carolina by myself and other scientists at UNC-Chapel Hill. This technology was refined and successfully commercialized through a Raleigh-based start-up company called Micell Technologies and was launched nationally through a new chain called Hangers Cleaners. Micell sold this garment care technology in 2001 to a company in Minnesota in order to focus on the use of CO2 in the microelectronics industry. Today there are over 70 Hangers Cleaners open around the country. The CO2 process used at Hangers just received the highest rating for dry cleaning methods from Consumer Reports (February 2003), even beating out perc.

Just two months ago, the State of California banned perc prior to making any investment by the state in cleaning up perc sites. Why might this be? Perhaps because, according to state authorities in Florida, even new perc-based dry cleaning plants installed after 1990 using supposedly "safe" state-of-the-art equipment are already contaminated. 

So why would North Carolina invest millions in cleaning up perc sites and still allow for perc to be used going forward? Greenpeace issued a "Report Card" in 2001 and gave Hangers' CO2-based dry cleaning process their highest grade, along with wet-cleaning methods. Perc and Green Earth, a flammable organic solvent, both received a failing grade.

If dry cleaning sites in North Carolina became contaminated with perc even when responsible dry cleaning operators used the level of stewardship suggested by perc and equipment manufacturers, why shouldn't the state request clean-up cost support from the manufacturers of perc like Dow Chemical and Vulcan Chemical?

Joseph M. DeSimone
Chapel Hill
(The writer is a Kenan professor of chemistry and chemical engineering at UNC-Chapel Hill and N.C. State University, director of the National Science Foundation Science and Technology Center for Environmentally Responsible Solvents & Processes, and chairman and co-founder of Micell Technologies.)

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10 March 2003:  Mentoring Seminar at NC State        Dr. Howard Adams will lead the opening discussion, "Mentoring of Graduate Students from Diverse Populations." He will also provide remarks at our luncheon and moderate a faculty/ student panel discussion.  Dr. Adams is the founding director of the GEM National Institute on Mentoring and the former Executive Director of the National Consortium for Graduate Degrees for Minorities in Engineering and Science (GEM). He was also a member of the U.S. Congressional Task Force on Women, Minorities and the Handicapped in Science and Technology, as well as Vice President for Student Affairs at Norfolk State University . He is currently president of Howard G. Adams and Associates, a consulting firm that provides professional development services to governmental, educational and industrial organizations.
   
     "Mentoring Graduate Students for Success" is co-sponsored by the NSF-funded NC Alliance to Create Opportunity through Education (OPT-ED), the NSF-funded Alliances for Graduate Education and the Professoriate Program, the NIH-funded Bioscience Research Initiative for Doctoral Graduate Education (BRIDGE) program, and the NC State Graduate School.
        Although this program will be held at NC State, faculty and postdoctoral associates from across North Carolina are invited to participate. Please note that transportation and necessary hotel costs for attendees from outside of the Raleigh-Durham area will be covered. Please visit our website at
http://www.fis.ncsu.edu/grad_fellows/opt-ed/faculty_mentoring/index.htm in order to register or get more information about this event.
   
     "Mentoring Graduate Students for Success" promises to be an excellent and informative program for both new and experienced faculty & post-docs.  If you have any questions about this event, please contact Dr. David M. Shafer, Assistant Dean, The Graduate School North Carolina State University at DAVID_SHAFER@NCSU.EDU or call (919) 515-7052. Or contact Ms. Tangie Gray, Coordinator of OPT-ED, at tangie_gray@ncsu.edu or (919) 515-2744.

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17 January 03:  UNC-CH 15TH and NCA&T 19TH FOR BLACK STUDENTS
Black Enterprise magazine has ranked UNC-CH 15th and NCA&T State U 19th in its biennial list of the 50 best colleges in the country for African-American students.

The ranking measures social and educational environments for black students, based on contact with 1,855 black college presidents, admissions directors and recruiters.  According to the magazine, the list includes accredited, four-year colleges that have a black enrollment of at least 3 percent or that are large and well known. The full list is in the magazine's January issue. www.blackenterprise.com  

13 January 03: Safety Alert from UNC-CH Chemistry Department
A TEFLON bottle containing about 5-10 grams of a newly synthesized peroxide (ethylperoxydicarbonate) in a 50 wt% hexane solution apparently detonated minutes after a student placed the container in a freezer. Fortunately, no one was injured and damage was minimal. We've been using this compound for several years without incident. The explosion sounded like a shot gun, the freezer door was blown open and other containers were ruptured. The secondary containers in use in the freezer helped to minimize damage. 

A similar incident was reported to have occurred years ago when a plastic bottle of about 200 g of solid, pure diisopropylperoxydicarbonate exploded when the freezer in which it was stored lost power. 

Researchers are advised to handle peroxides with great care, including appropriate hand and eye protection and shielding. It is probably fair to say that there is no such thing as a totally safe organic peroxide! Even those which we have come to regard as innocuous can become dangerous if contaminated, shocked, heated, etc. 

We will conduct an investigation, including UNC-CH Chemistry Dept. laboratory safety management, to make recommendations regarding future safe storage and use of peroxides as initiators.

03 January 03:  Microchips' Heavy Burden article in Chemical & Engineering News
New fabrication technologies likely will reduce high material inputs needed to make chips

STEPHEN K. RITTER, C&EN WASHINGTON

The information technology revolution based on the microchip has helped society in innumerable ways through computers and consumer electronics. The high value placed on microchips, coupled with their small size, gives the impression that they deliver their benefits with a negligible impact on natural resources and the environment. To the contrary, however, chip production uses many chemicals and consumes a disproportionate amount of energy and water.

These are the observations made in a new study in which researchers conducted a life-cycle analysis of microchips and found that producing a 2.0-g chip requires at least 1.7 kg of chemicals and fossil fuel inputs [Environ. Sci. Technol., 36, 5504 (2002)].

"The public needs to be aware that technology is not free," notes the study's lead author, Eric D. Williams, project coordinator for information technology and the environment at United Nations University, in Tokyo. "The environmental footprint of a microchip is much more substantial than its small physical size would suggest."

The study has important implications for the broader use of product life-cycle analysis as a tool to assess advances toward achieving global sustainable development, Williams and his coauthors suggest. This is particularly important for tracking dematerialization, the concept that technological progress is expected to bring about a reduction in the amount of natural resources consumed to produce commodity goods.

So far, advances in microchips have not resulted in significant reduction of material inputs to make them. But new technologies are being developed that will begin to make progress in that direction. These changes, however, are primarily the result of the semiconductor industry's need to overcome technical obstacles rather than a focus on cost savings and better environmental performance.

Fabrication of integrated circuits relies on hundreds of steps involving photolithography on a high-purity silicon wafer to define the shape and pattern of circuit features. Many circuits are made on a single wafer, which is dice to separate the individual rectangular circuits that are then encased in a protective plastic cover

with external leads--the familiar computer chip. Chip manufacturing primarily uses wet-chemical processing involving hydroxylamines, mineral acids, elemental gases and organic solvents during the various stages. In the process, a copious amount of deionized water is needed for rinsing.

Williams and his colleagues analyzed limited process data from several sources to come up with estimates of the aggregate consumption of materials needed to manufacture a standard 32-megabyte chip fabricated on a 200-mm silicon wafer. At a minimum, each 2.0-g chip requires 72 g of chemicals and 1.6 kg of fossil fuel for its fabrication and projected use over a four-year lifetime. In addition, 700 g of elemental process gases and 32 L of water are required but are not included in the weight estimate because they can be recovered or are released harmlessly to the environment.

The industry can't just stop making and using chips because the environmental burdens are considered high.

A MAJOR COST for chip fabrication relates to the energy needed to prepare ultrapure silicon wafers and to operate fabrication clean rooms. Water purification and consumption is an additional heavy burden. A typical plant processing 40,000 silicon wafers per month consumes several million gallons of water per day.

The telling statistic from the study is the 630:1 ratio of the weight of chemicals and fossil fuel needed to make a chip versus the final weight of the product. This intensity of use, which is a lower-limit estimate, is orders of magnitude greater than that of other goods, Williams points out. For comparison, cars are much heavier and consume a greater amount of materials--including some microchips--in their production, but the corresponding ratio is only 2:1.

The industry can't just stop making and using chips because the environmental burdens are considered high, Williams says. Instead, the scientific community should work on minimizing those burdens while maximizing the benefits of information technology. "For microchips, extending the lifetime of their use is perhaps the lowest hanging fruit for reducing burdens," he notes.

"The 1.7 kg to 2.0 g comparison is very eye-catching and will stick in the minds of most people," notes Dennis L. Hjeresen, senior program manager for risk reduction and environmental stewardship at Los Alamos National Laboratory (LANL) and director of the American Chemical Society's Green Chemistry Institute. "There are several points to make in using this comparison to bring about change."

SUPER CLEAN Supercritical CO2 technology developed by DeSimone's group in conjunction with Micell Technologies provides water-free method to clean etch residues during chip fabrication.
One point is that life-cycle analysis should be demanded of all consumer products, Hjeresen says. "Many chemical and consumer products don't perform much better than semiconductors. These high-value products often skate on environmental concerns because of their inherent 'return.' "

This is the case in electronics, he says, with a highly relevant parallel in pharmaceuticals, agricultural chemicals, and photographic processing. A key concern is the high volume of water used in the semiconductor industry, which is mostly located in water-poor regions.

Semiconductor fabrication firms are working toward reducing materials use. However, significant changes in current consumption rates are expected to come about not from a focus on improving environmental performance but rather from the semiconductor industry running into a limiting technical problem.

AS POROUS low-dielectric materials are starting to be used and chip architectures become ever smaller--widths below 130 nm are needed for new generations of integrated circuits--the surface tension of water no longer will allow it to be readily removed from pores or to penetrate smaller spaces. The smaller architectures also
do not have sufficient mechanical integrity to withstand processing with high-surface-tension liquids.

International Sematech, a research consortium formed by the semiconductor industry to help set standards, demonstrate new technology development, and solve common problems, has targeted supercritical CO2 as one enabling process to get around the water problem.

Supercritical CO2 has very low surface tension and a gaslike viscosity. Those properties allow removal of photoresist masks as well as post-etching and other treatment residues from small structures using fewer chemicals and without the need for water. This target has the entire semiconductor industry--chip makers, companies that provide machines for fabricating chips, and industrial gas suppliers--working on developing solutions.

One of these solutions is SCORR (Supercritical CO2 Resist Remover), a process originally developed at LANL that has been automated by SC Fluids with its Arroyo System (C&EN, July 1, page 26). SC Fluids has teamed with Air Products & Chemicals, ATMI, and IBM to complete the development of Arroyo, according to David J. Mount, SC Fluids' vice president of strategic development.

Air Products will supply bulk gases and work on gas purification and recycling issues, he says. ATMI, a supplier of specialty materials and equipment to the semiconductor industry, is helping SC Fluids to develop cosolvents. Air Products and IBM are currently testing the Arroyo system, Mount says, and the first commercial units are expected to be in operation in 2003.

Dainippon Screen and Tokyo Electron Ltd. are other companies in the advanced stages of developing supercritical CO2 semiconductor processing methods. For its wafer-cleaning process, Dainippon is working with Kobe Steel and Ashland Specialty Chemical, a leading supplier of photoresist strippers. Tokyo Electron Ltd., through its subsidiary Supercritical Systems, is working with industrial gas supplier Praxair and engineering firm Uhde.

Eventually, all water- and solvent-based processing of integrated circuits--metal and polymer deposition, chemical mechanical planarization, lithography, and cleaning--could be carried out by dry processing using CO2, notes Joseph M. DeSimone, a professor of chemistry at the University of North Carolina, Chapel Hill, and a professor of chemical engineering at North Carolina State University. Cleaning is the first level of focus, DeSimone says. "But once that foothold is established, it will become the foundation for the development of many other dry technologies."

DeSimone, who has developed several supercritical CO2 technologies, is also director of the National Science Foundation's Science & Technology Center for Environmentally Responsible Solvents & Processes. The NSF center is building a demonstration facility for the "dry fab of the future" on NC State's campus, DeSimone says. He envisions that a completely integrated facility could be developed in the next 10 to 15 years where all semiconductor processing could be done in a closed system without the need for shuttling wafers between dry fabrication steps and wet-chemical processing and rinsing steps. "Overall, such a system would eliminate water and organic solvents and save on building and operating costs for clean rooms," he notes.

Micell Technologies, which has licensed several of DeSimone's developments, is currently working with an industrial gas company and machine manufacturers to develop some of the new dry processes that will be incorporated into commercial factories and the new demonstration facility. These processes include using CO2 in both the liquid and supercritical states along with surfactants or etchants, depending on the fabrication step. DeSimone's group is also working to develop CO2-processible photoresists, copper-oxidizing and -chelating agents and other compounds to optimize dry processing.

A dry fabrication facility would fundamentally transform the way that integrated circuits and memory chips are manufactured, not just from a pollution-prevention perspective but also from an economic perspective," DeSimone says.

Although supercritical CO2 solves the semiconductor industry's water problem in a big way--by eliminating water--there still will be significant energy consumption required for handling CO2. However, because of CO2's properties, energy use is expected to be less than that for wet processing. These properties also should allow easier separation and recovery of CO2 and residual materials by methods that are unavailable to water- and solvent-based processes.

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