Project Team 1 (Macromolecular Synthesis and Engineering)

Overall Objectives
Composition
Program Summary Table
Overview Research Project Teams

Project Team 1 Overall Objectives

To develop a fundamental understanding of kinetic and transport mechanisms and  prediction of partition coefficients to enable engineering of CO2-based polymerization processes

In a way that:

·       Provides basic data on end-group mobility and monomer diffusion rates in CO2-swollen polymerization systems

·        Develops basic data on reaction kinetics and chemical equilibria

·        Develops basic data for membrane separation of CO2 from monomers

·        Develops fundamental understanding and data regarding transport of gases in polymers supporting membrane separations

·       Employs a systems approach, integrating innovative chemistry with new engineering technology such as membrane separations for optimum process efficiency

·        Provides new laboratories for in situ, high-pressure analytical studies and for measuring static and dynamic interfacial interactions of liquid and supercritical CO2 fluids with various surfaces

So that the viability of non-polluting CO2-based polymerization processes with low capital investment and low operating costs will be clear and attract commercial support.

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Project Team 1 Composition

Implementation Domain: Fundamentals of Molecular Synthesis and Process Design
Project Team: Macromolecules
 
Leadership: George W. Roberts, NCSU
William J. Koros, UT-A
   
Group leader: Sarah Folk, UNC
 
Members:
Aruna Boddu, A&T
Angela Hines, A&T
Sylvain Gerard, NCSU NCSUCoray Colina, NCSU
Karen Kennedy, NCSU
Martin Lisal, NCSU
Tao Liu, NCSU
Joseph Royer, NCSU
Chunmei Shi, NCSU
Lou Wojcinski, NCSU
Jackie Behles, UNC
Stephanie Crette, UNC
Dolores Herman-Wynn, UNC
Jennifer Polley, UNC
Poovath.  Raveendran, UNC
Bin Xu, UNC
Haruhiko Yashiro, UNC
Luke Zannoni, UNC

Coordinated members:
Jim Alstrum, UNC
Karen Erford, UNC

 
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Project Team 1 Program Summary Table

Prog #  Program Title  P. I./Affiliation Investigators
A&T 04 Separation & recovery of SCF CO2Using Microporous Ultrafiltration and Nanofilitration Membranes
 
Illias, A&T Aruna Boddu, A&T
NCSU 01 SAFT models for surfactants and Polymerization Systems
 
Gubbins, NCSU Coray Colina, NCSU
NCSU 03 Micellization Processes in CO2 Lattice Monte Carlo Simulations and Molecular Modeling
 
Gubbins, NCSU
Hall, NCSU
Martin Lisal, NCSU
NCSU 13 Phase Equilibrium: Polymer/Monomer/Initiator in CO2 Systems
 
G. Roberts, NCSU
DeSimone*1, UNC
Karen Kennedy, NCSU
NCSU 14 CSTR/Reactor Calorimetry Studies of Polymerizations in CO2
 
G. Roberts, NCSU
DeSimone*1, UNC
Tao Liu, NCSU
UNC 01 Partition Coefficient Studies in CO2 Using Pulsed Field Gradient NMR
 
Johnson, UNC
DeSimone*1, UNC
Bin Xu, UNC
UNC 05 NMR Studies of Structure and Dynamics of CO2 Systems
 
Wallen, UNC TBD
UNC 09 Application of EPR to Measure Kinetics of Polymerizations in CO2
 
Forbes, UNC Haruhiko Yashiro, UNC
UNC 14 Synthesis of Cationic Silicone-based Surfactants/Nanoporous Materials
 
DeSimone*1, UNC Sarah Folk*2, UNC
UNC 15 New Hydrocarbon based Surfactant Systems
 
DeSimone*1, UNC Jeniffer Polley, UNC
UT-A 08 High pressure & SC CO2 separations
 
Koros, UT-A Shilpa Damle, UT-A
*1 Faculty Project Team Leaders.
 
*2 Student Project Team Leaders.

Go to:
Project Team 2 Composition
Project Team 3 Composition
Project Team 4 Composition
Project Team 2 Program Summary Table
Project Team 3 Program Summary Table
Project Team 4 Program Summary Table
 
Educational Outreach and Social Science Program
 
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