The CERSP seeks to use the educational process at all levels to build support for implementation of “green chemistry”.  Our initial focus is on collaboration and innovation because these are of global importance, typically are not taught in academic programs, and are undergoing change and transformation in today’s world.  We seek to provide a new generation of students with both the technical and social tools to effect this transition. Specifically our objectives are to:

bulletPrepare students broadly for successful careers in industry, academia and government
bullet Help students, faculty and scientists contribute to the Center’s immediate success by providing them opportunities to learn and practice a variety of strategies and skills.

            We’re supporting internships to encourage undergraduates and high school students to choose scientific careers. These programs are heavily weighted towards historically underrepresented segments of society. 

2006
During 2006 thirteen undergraduate and two high school students received a challenging and educational summer research experience sponsored by CERSP 

·        Some 1010 interns applied for internships through the joint NSF STC recruitment site.

bullet18 interns picked CERSP as 1st choice for summer 2006 experience and 26 interns picked CERSP as 2nd or 3rd  choice 
bulletInvitation Letters sent to 15 students; 14 accepted.  6 students accepted appointments at NCSU REU and 8 students accepted appointments at UNC
bullet79% were from underrepresented groups including six African-Americans (four males), seven females, and one Hispanic.
bullet Leveraging of existing programs continues in order to reach nationally high school and undergraduate students:
bulletProject SEED (http://www.projectseed.org/) at UNC-CH (focusing on African-American high school students); one SEED student accepted at UNC this summer
bullet We continue to seek students from the following programs but had none in 2006
bullet SPGRE program sponsored by Prof. Henry Frierson at UNC-CH (http://www.unc.edu/depts/res/spgre.htm  and the related Research Education Support (RES) Program (http://www.ibiblio.org/res/);
bullet NSF STC Undergraduate Research Coordination program (http://www.nsfstc.org/centers.htm)

A new REU proposal was submitted by CERSP partner, NC State University, and was awarded.  Six of the students listed below were funded by this REU.

UNC Activities                                                                                     Target Date 2006

Welcome Luncheon (Spanky’s Restaurant)                                             May 22

Safety Overview                                                                                          May 22

Orientation                                                                                                   May 22

Entrepreneurs’ Sessions (Desimone/Carbonell)                                    June 13

Industrial Tours (Glaxo Smith Kline)                                                          June 20

Tour of New Science Complex                                                                  July 7

Intern Group Meetings                                                                                 Weekly

CERSp Videoconference Group Meetings                                             Weekly

Final Presentations                                                                                     July 19

Exit Interviews                                                                                              July 19

Awards Luncheon                                                                                        July 21

 

NCSU REUs Activities                                                                          Target Date 2006

Campus Laboratory Safety Orientation                                                    June 2

Welcome Reception for students and mentors -                                     June 2

Group Picnic at Michael Paesler's home                                                June 2

Research Ethics Symposium      

Natural History Museum behind the scene tour –                                   June 17

Trips to CISCO, EPA, GlaxoSmithKline, etc –       

Beach day trip on Saturday                                                                       July 1

Picnic with fireworks at Fairgrounds                                                        July 4

Hiking Umstead Park –                         

Poster Training Sessions –         

Durham Bulls Game –-                                                                              July 7

GRE Workshops              –

 

Prof. Darlene Taylor, RICHES Director and leader of our summer program, met the summer interns weekly.  She had each of them to discuss with the group their research progress.  This appeared to be an excellent means to build continuity, community and to identify problems promptly, before they became disruptive. 

 

Last,

First

Undergrad Institution

Major

Status

Site

Faculty Mentor

Research Topic

Alford,#

Jonathan

NC A&T State University

Chem Eng

Soph

UNC-CH

Sheiko

Conditions for Lift off and Adsorption of Polymers on Surface

Bergquist,

Curtis

UNC at Chapel Hill

Music

Soph

UNC-CH

Joseph DeSimone

PRINTing Particles

Campbell,

Candice

New Mexico State U

Physics

Fresh

NCSU

Peter Kilpatrick

Low Temperature Radiation Upgrading of Heavy Oils and Bitumen

DeLeon,

David

UNC at Chapel Hill

Chem

Junior

UNC-CH

Joseph DeSimone

Fluoropolymers for PRINT

Dunn,

Erin

UNC-Chapel Hill

Chem

Junior

UNC-CH

Joseph DeSimone

Applying Nano-technology to High Surface Area Fuel Cells

Fakhouri,

Sami

UNC at Chapel Hill

Chem

Soph

UNC-CH

Joseph DeSimone

Drug Releasing Polymer Particles via PRINT

Haithcock,

Brandi

Southern Alamance High School, Graham, NC

NA

High

School

UNC-CH

Joseph DeSimone

Magnetopolymer Nanocomposites from P.R.I.N.T. Technique

Kubinski,

Susan

Arizona State University

Chem Eng

Soph

NCSU

Hasan Jameel

Conversion of Mixed Office Waste Paper to Ethanol

Montanez,

Gabriela

Arizona State University

Chem Eng

Soph

NCSU

Dr. Peter Kilpatrick

CO2 Soluble GRAS Solvents for Extracting Nutraceuticals by a Gas Anti-Solvent Process

Montgomery,

Aaron

University of Virginia

Mech Eng

Junior

UNC-CH

Joseph DeSimone

Thermodynamics behind the PRINT process

Morton,

Leslie

UNC at Chapel Hill

Polymer Chem

Soph

UNC-CH

Joseph DeSimone

Alternative Fluoropolymers to the Avoid Challenges Associated with PFOA

Paul, #

Evan

NC A&T State University

Chem Eng

Soph

NCSU

Peter Fedkiw

Direct Methanol Fuel Cell

Petschke, Eric

NC State University

Chem Eng

Senior

NCSU

Gregory Parsons

Principles of Solar Cells Fabrication of Organic Solar Cells

McLaughlin, Stephen

NC State University

Chem Eng

Soph

NCSU

David Ollis    

Photocatalytic Regeneration of Carbon Absorption System       

Muse, * Carletta Devonne

-------------

-------------

High

School

UNC-CH

Valerie Ashby

Biosorbable particles

 

* Project SEED

# EXPERT Student from NCA&T

Exit interviews were held with summer interns at UNC-CH.  A summary of comments is given in the following table.  All of the students said that the experience interested them in graduate school or medical research for the first time or reinforced their interest.  A summary is given below in the Table.

 

Table  2006 Summer Program Exit Interview Summary

 

Ø      Administrative issues

o       Salary issues adequately explained except withholding requirements

o       Could salary be increased for more experienced students?

o       No food in dorms on weekends, an inconvenience

o       Locate away from summer sports camp participants

o       Parking is expensive; can we provide or recommend options?

o       They claim they did not receive abstracts of videoconferences beforehand; are they on our normal distribution list?

Ø      Orientation

o       Overall good.  Might include more about the STC and website

Lab and safety (plus video) very good.  Having individual mentors helped

Ø      Planning

o       Initial planning sessions good; expectations clear

o       Could have better informed and trained mentors beforehand

o       All interns felt assignments were appropriate for their interests and abilities

Ø      Entrepreneurship

o       Excellent.  Even those not interested in doing it themselves were interested to see  how things work

o       Unlike previous years, most students were aware of such activities.

Ø      GlaxoSmithKline tour

o       Mixed.  Most felt that presentations were interesting but lab tours were too long, with too much time spent on seeing instruments they already knew about. They would have preferred seeing an actual plant. Perhaps we should consider inquiring about Stockhausen in Greensboro.   

Ø      Weekly intern meetings

o       These and group meetings were more meaningful and useful than Thursday videoconferences, which lacked enough background to be useful

o       Should be scheduled on Tuesday (or some day other than Thursday)

o       Should have fewer speakers or perhaps share reporting

Ø      Thursday CERSP

o       Poor.  Most felt they were a waste of time except when members of their group spoke.  Would rather spend the time in the lab. They did not have the background to understand content.

o       On the other hand, as everyone else was in the videoconference they didn’t think it would be a good idea for them to be in the labs alone.

Ø      General comments

o       Probably not appropriate for high school (at least not at rising junior level)

·        Starts too early (they’re still in school)

·        Don’t have the background

o       Interest in graduate school increased for undergrads

·        Confirmed interest for those unsure

o       Ten weeks about right to complete lab project with all of the external activities

o       Mentors were excellent!

o       Would have liked more social activities (UNC-CH group, NC State okay)

 

2004

bullet

CO2 Based Sterilization  Michael John Cangelosi, UNC-Chapel Hill (CERSP Funded)
    Mentors: Colin Wood and Professor Joseph DeSimone
 

bullet

Perfluoropolyether Fouling Release Coatings Johnaustin Chapman, Cedar Ridge High School (PROJECT Seed Funded)
    Mentors: Jason Yarbrough and Professor Joseph DeSimone
 

bullet

Fractionation of PDMS in CO2 Compared to Fraction by Organic Solvents  Emily Connelly, Northern High School (PROJECT Seed Funded)
    Mentors: Zhilian Zhou and Professor Joseph DeSimone
 

bullet

Photoluminescence of Semiconductor Zinc Oxide Nanorods  Desmond Harvey, Langston University (CERSP Funded)
    Mentors: Lei Zhang and Professor Edward T. Samulski
 

bullet

Synthesis of Functionalized Biomaterials  Noah D.Meeks, Northern Kentucky University (CERSP Funded)
    Mentors: Janet Maegerlein and Professor Valerie Ashby
 

bullet

Copper CMP in CO2: Slurry Stabilization Lauren Ellen Portnow, UNC-Chapel Hill (CERSP Funded)
    Mentors: Pamela Visintin and Professor Joseph DeSimone
 

bullet

Copper Etching Using Micellar Water in Carbon Dioxide Systems  Renee C. Smith, UNC-Chapel Hill (Research Education Support Funded)
    Mentors: Ginger Denison and Professor Joseph DeSimone
 

bullet

PDMS as a Fouling Release Coating  David Robinson Snead, UNC-Chapel Hill (ONR Funded)
    Mentors: Jason Rolland and Professor Joseph DeSimone

2001

bullet

Thermodynamic Measurements of CO2 Containing Systems  Alessandra Carreon and Vinayak Kabadi

bullet

Designing Photoresist Systems for Carbon Dioxide  Bryant Suitte, Devin Flowers, and Joseph M. Desimone

bullet

Characterization of Phase Behavior of Homopolymers Used for Coating Applications in Carbon Dioxide
 Brooke Hester, Gerardo Montero, Robert Harris

bullet

Real-time Rate Monitoring of Decontamination of Solid Surfaces in SCCO2   Israel Vargas Jr., Paa-Joe Akoto-Ampaw, and Christine S. Grant

bullet

Continuous and Batch Polymerization of Vinylidene Fluoride in CO2
Nathan Lechene, Lou Wojcinski, and George Roberts

bullet

Investigation of Dye-Fiber Reactions in SC-CO2
Nneka C. Ubaka-Adams, Ahmed El-Shafei, Gerardo Montero, and David Hinks

bullet

Characterization of Phase Equilibrium Associated With Heterogeneous Polymerizations in Supercritical Carbon Dioxide
Shama Karu, Karen Kennedy, and George Roberts  

bullet

Synthesis of Cationic Nanogels Through Microemulsion Polymerization
Tamona Williams, Karen Erford, J.M. DeSimone, and Michael Rubenstein

bullet

Synthesis of Fluorinated Homopolymers by ATRP and the Determination of Their Extent Solubility in CO2 by Light ScatteringTiffani Nicole Bailey, Sarah L. Folk, J. M. DeSimone

bullet

Generation of Microcellular Polymeric Foams (MPFs) in Liquid and Supercritical Carbon Dioxide
John Coughlan, Srinivas Siripurapu, Saad Khan and Richard Spontak