Publications and Presentations

Partially Supported Activities 11/1/99-7/31/00

 

Publications

Preprints

Meetings, Presentations, Invited Lectures made since advent of CERSP

Patents

 

Publications

[list with online Journals]

"Toroid cavity Detectors for High-Resolution; Momot, K.I.; Binesh, N.; Kohlmann, O.; Johnson, C.S. Jr.; J. Magn. Reson.142; 2000, 348-357 NMR Spectroscopy and Rotating Frame Imaging: Capabilities and Limitations"

 

"A Polymer NMR Cell for the Study of High-Pressure and Supercritical Fluid Solutions, Analytical Chemistry"; Wallen, S.L.; Schoenbachler, L.K.; Dawson, E.D.; Blatchford, M.A.; In Press

 

"Spectroscopic Approaches for the Study of High-Pressure Fluid Systems, SPIE-The International Society of Optical Engineering BIOS"; Wallen, S.L.; Blatchford, M.A.; Dawson, E.D.; Schoenbachler, L.K.; In Press.

 

"Block Copolymers as Stabilizers in Supercritical Fluids"; Johnston, K.P.; Current Opinion in Colloid and interface Science. Submitted, 2000.

 

"Percolation in Concentrated Water-in-Carbon Dioxide Microemulsions"; Lee, C.T.; Bhargava, P.; Johnston, K.P.; Submitted to Journal of Physical Chemistry B., 2000. [click to read the abstract]

 

"In-Situ investigation on the Mechanism of Dispersion Polymerization in Supercritical Carbon Dioxide"; Li, G.; Yates, M.Z.; Johnston, K.P.; Macromolecules. 2000, 33, 4080-4014. [click to read the abstract]

 

"Steric Stabilization of Colloids by Poly(dimethylsiloxane) in Carbon Dioxide: Effect of Cosolvents"; Yates, M.Z.; Shah, P.S.; Johnston, K.P.; ; Lim, K.T.; Webber, S.E.; Colloid Interface Science. 2000, In Press.

 

"Structure of Diblock Copolymers in Supercritical Carbon Dioxide and Critical Micellization Pressure"; Triolo*, R.; Triolo, A.; Triolo, F.; Steytler, D.C.l Lewis, C.A.; Heenan, R.K.; Wignall, G.D.; DeSimone, J.M.; The American Physical Society. 2000, 61, 4, 4640-4643.

 

"Qens From Polymer Aggreates in Supercritical CO2"; Triolo, R.; Arrighi, V.l Triolo*, A.; Migliardo, P.; Magazu, S.; McClain, J.B.; Betts, D.; DeSimone, J.M.; Middendorf, H.D.; Physica B. 2000, 276-278, 386-387.

 

"Preparation of Silicone-Graft Copolymers by Homogeneous Radical Copolymerization in Supercritical Carbon Dioxide"; Shiho, H.; DeSimone, J.M.; Journal of Polymer Science Part A: Polymer Chemistry. 2000, 38, 1139-1145.

 

"Dispersion Polymerization of Styrene in Supercritical Carbon Dioxide Utilizing Random Copolymers Including Fluorinated Acrylate for Preparing Micronized Polystyrene Particles"; Shiho, H.; DeSimone, J.M.; Journal of Polymer Science Part A: Polymer Chemistry. 2000 28, 1146-1153.

 

"Dispersion Polymerization of Acrylonitrile in Supercritical Carbon Dioxide"; Shiho, H.; DeSimone, J.M.; Macromolecules. 2000, 33, 1565-1569. [click to read the abstract]

 

"Synthesis of Fluoropolymers in Liquid and Supercritical Carbon Dioxide Solvent Systems"; Young, J.P.; Romack, T.J.; DeSimone, J.M.; Fluoropolymers. 2000, 13, 191-205.

 

"Critical Micellle Denisty for the Self-Assembly of Block Copolymer Surfactants in Supercritical Carbon Dioxide"; Triolo, F.; Triolo, A.; Triolo*, R.; Londono, J.D.; Wignall, G.D.; McClain, J.B.; Betts, D.E.; Wells, S.; Samulski, E.T.; DeSimone, J.M.; Lanmuir. 200, 16, 416-412.

 

“Polymerizations in Supercritical Carbon Dioxide”; Kendall, J.L.; Canelas, D.A.; Young, J.L.; DeSimone, J.M.; Chemistry Review. 1999, 99, 543-563.

 

“Small Angle Neutron Scattering from Polymers in Supercritical Carbon Dioxide” Londono, J.D.; Wignall, G.D.; McClain, J.B.; Betts, D.E.; Canelas, D.A.; DeSimone, J.M; Samulski, E.T.; Triolo, R.; Neutron News 1999, 10/2, 10-11.

 

“Preparation of Micron-Size Polystryene Particles in Supercritical Carbon dioxide”; Shiho, H.; DeSimone*, J.M.; Journal of Polymer Science I. Part A 1999, 37, 2429-2438.

 

"The Crystallization and Solid State Polymerization of Poly(bisphenol A. carbonate) Facilitated by Supercritical CO2"; Gross, S.; Roberts, G.W.; Kiserow, D.J; DeSimone, J.M.; Macromolecules 2000, 33, 1, 40-45. [click to read the abstract]

 

"Dispersion Polymerization of 1-Vinyl-2-Pyrrolidone in Supercritical Carbon Dioxide"; Carson, T.; Lizotte, J.; DeSimone, J.M; Macromolecules, 2000, 33, 6, 1917-1920. [click to read text (no online abstract)]

 

“Synthesis of Fluoropolymers in Liquid and Supercritical Carbon Dioxide Solvent Systems” Young, J.P.; Romack, T.J.; DeSimone, J.M.; Fluoropolymers, 2000, 13, 191-205.

 

 “Decomposition of Polymerization Initiators in Supercritical CO2: A Novel Approach to Reaction Kinetics Using a CSTR”, Charpentier, P. A., DeSimone, J. M.; Roberts, G. W., accepted for publication in Chemical Engineering. Science.

 

“Continuous Precipitation Polymerization of Vinylidene Fluoride in Supercritical Carbon Dioxide: Modeling the Rate of Polymerization”, Charpentier, P.A., DeSimone, J. M.; Roberts, G. W.; Accepted for publication in Ind. Eng. Chem. Res.

 

“Surface-Mediated Reactions.  9.  Selective Oxidation of Amines to Hydroxylamines”,  Kropp, P. J. Accepted for publication in J. Org. Chem.

 

"Carboxylesterase from Sulfolobus solfataricus P1. Meth. Enzymol. 330"; Sehgal, A.C.; Callen, W.; Mathur,E.J.; Short, J.M.; Kelly, R.M.; In Press.

 

"Surfactant/Supercritical Hydrocarbon Cleaning of Metallic Substrates"; Roberts, K.L.; Spence, T.S.; Forbes, J.E.; Pritchard, V.E.; Saunders, K.B.; White, G.L.; Industrial and Engineering Chemistry Research (Accepted)- Partial Support with NASA.

 

"Dynamics of Entangled Solutions of Associating Polymers"; Rubinstein, M.; Semenov, A.N.; Submitted to Journal of Polymers Science B. Polymers Physical.

 

“High Pressure Rheology of Polystyrene Melts Plasticized with CO2: Experimental Measurement & Predictive Scaling Relationships"; Royer, J.R.l gay, Y.J.; DeSimone, J.M.; Khan, S.A.; Submitted to J Polym. Sci. B Polym. Phys.

 

Gray, D. O.  Government-sponsored industry-university cooperative research:  An analysis of cooperative research center evaluation approaches. Research Evaluation, 9, 57-67.

 

Gray, D. O., Lindblad, M. & Rudolph, J. (in press). University-based industrial research consortia: A multivariate analysis of member retention. Journal of Technology Transfer

 

Sonnenwald, D.H., Wildemuth, B.M., Kindon, V., Brassell, E., Harmon, G. (in press) An example from a study of lower socio-economic students’ information seeking behavior. Proceedings of the Information Seeking in Context 2000 Conference.

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Preprints

 

“Fluoropolymers enabling the CO2 Technology Platform” DeSimone, J.M.; Polymers in Supercritical Fluids Hawaii Millennium Meeting, December 10, 2000.

 

“Scattering studies of mixed micelles in supercritical carbon dioxide” Taylor, D.K.; Wells, S.; Yoshida, E.; Adam, M.; Rubinstein, M.; DeSimone, J.M. ”  Polymers in Supercritical Fluids Hawaii Millennium Meeting, December 10, 2000.

 

“Synthesis of High Molecular Weight Polycarbonate by Solid State Polymerization” Polymers Gordon Conference, Gross, S.M.; Roberts, G.W.; Kiserow, D.J.; DeSimone, J.M. June 2000.

 

“Broadening of Molecular Weight Distribution in Solid State Polymerization due to Condensate Diffusion”; Polymers Gordon Conference, Goodner, M.D.; Gross, S.M.; DeSimone, J.M.; Roberts, G.W.; Kiserow, D.J. June 2000.

 

“Novel Multifunctional Perfluoropolyethers for Low-Surface-Energy Materials” Polymers Gordon Conference; Bunyard, W.C.; Carbonell, R.G.; DeSimone, J.M. June 2000.

 

“Non-Homogeneous Aggregates in Supercritical Carbon Dioxide”, US- Pacific Rim Chemical Societies meeting in Hawaii, December 2000.

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Meetings, Presentations, Invited Lectures made since advent of CERSP

 

Diffusion and Dynamics of Fluorinated Polymers in Supercritical Carbon Dioxide; Poster at the 41st Experimental NMR Conference. K. Nagashima, E. Yoshida, J.M. DeSimone, and C.S. Johnson, Jr.,  Book of Abstracts, 41st Exp. NMR Conference, April 9-14, 2000 B Asilomar Conference Center

 

Colloids in Supercritical Fluids: Fundamentals and Applications, 5th. Int. Symp. On Supercritical Fluids, Atlanta, GA, April 10, 2000.  Johnston, K. P.

 

Future Directions in Supercritical Fluid Science and Technology: The Third Decade, Plenary Closing Lecture, 5th. Int. Symp. On Supercritical Fluids, Atlanta, GA, April 12, 2000.  Johnston,

K. P.

 

Colloids in Supercritical Fluids: Fundamentals and Applications, 13th International Symposium on Surfactants in Solution, Gainesville, FL, June 13, 2000.  Johnston, K. P.

 

Semiconductor Synthesis in Supercritical Fluids, Am. Inst. Chem. Eng. Ann. Mtg. Dallas, TX, Nov. 3, 1999 (K. Johnson, C. Doty, P. Bhargava, J. Holmes, B. Korgel, and K. Ziegler)

 

Formation, Stability and Flocculation of Water in Supercritical Carbon Dioxide Emulsions, Am. Inst. Chem. Eng. Ann. Mtg., Dallas, TX, Nov. 3, 1999  (K. Johnson, P. Psathas, and S. daRocha)

 

Ambidextrous Surfactants for Polymer Latexes in Either Carbon Dioxide or Water, Am. Inst. Chem. Eng. Ann. Mtg., Dallas, TX, Nov. 2, 1999  (K. Johnson, G. Li, and M. Yates)

 

Interfacial Activity of Perfluoropolyether Surfactants at the CO2-Water Interface, Am. Inst. Chem. Eng. Ann. Mtg., Dallas, TX, Nov. 3, 1999  (K. Johnson, S. daRocha, and P. Psathas)

 

Wet Chemical Synthesis of Luminescent Silicon Quantum Dots,  Am. Inst. Chem. Eng. Ann. Mtg., Dallas, TX, Nov. 3, 1999  (K. Johnson, B. Korgel, C. Doty, K. Ziegler, and J. Holmes)

 

Steric Stabilization of Colloids by Poly(dimethylsiloxane) in CO2: Effet of Cosolvents, Am. Inst. Chem. Eng. Ann. Mtg., Dallas, TX, Nov. 4, 1999  (K. Johnson, K. Lim, S. Webber, and M. Yates)

 

Summary of Keith Johnston’s Research Projects, University of Texas Separations Research Program, a group of 30 companies, on April 18, 2000.

 

Spectroscopic Approaches to the Study of Interfaces in Compressible Media, The Fifth International Symposium on Supercritical Fluids, Atlanta GA, April 9-11 (Wallen, S. L.)

 

Spectroscopic Approaches for the Study of High-Pressure Fluid Systems, SPIE BIOS 2000, The International Symposium on Biomedical Optics, San Jose, CA, January 22-28, 2000 (Wallen,

S. L.)

 

Sehgal, A.C., and R.M. Kelly. Biochemical characterization of a carboxylesterase from the hyperthermophilic archaeon Sulfolobus solfataricus P1. Middle Atlantic Biochemical Engineering Consortium Annual Meeting, University of Delaware, April 2000.

 

 

The Carbon Dioxide Technology Platform (DeSimone, J. M.)

-                      AIChE & Scientific Advisory Board Mtg. Nov. 4-5, 1999

-                      NSF STC Meeting in Washington, November 17, 1999

-                      Fisher Lecture, Roanoke College, VA: December 8, 1999

-                      SNS Groundbreaking Luncheon: Neutrons for the 21st Century, Oak Ridge, Tennessee: December 14-15, 1999

-                      UNCW Symposium on Chemistry and Biochemistry, Wilmington, NC: January 27-29, 2000

-                      DuPont Seminar, Experimental Station: February 1, 2000

-                      Ashland Specialty Chemical Co., --and R. G. Carbonell, February 24, 2000

-                      University of Buffalo Foster Colloquium Series Seminar March 1&2, 2000

-                      AIChE Conference, Atlanta: March 5-9, 2000

-                      American Chemical Society Meeting at Anaheim, California March 26-30, 2000

-                      The 5th International Symposium on Supercritical Fluids  (ISSF) April 8-12, 2000

-                      MIT  Seminar in Environmental Chemistry and Polymer Science Seminar April 21, 2000

-                      Johnson & Johnson Co.

-                      Gordon Conference on Polymers Connecticut,  The CO2 Technology Platform:  The Role of Basic Science to Support Environmentally Friendly Manufacturing Technologies,  June 10-13, 2000

-                      IBM, June 14-15, 2000

-                      First Symposium Frontiers of Chemistry, July 6-10, 2000

-                      PPG Pittsburgh, July 18, 2000

-                      Symposium “Enviro-Compatiable Synthesis and Processes:  Targeting Sustainability August 20-25, 2000 Washington DC

 

Kennedy, K. A., Roberts, G. W., and DeSimone, J. M., “Continuous Precipitation Polymerization of Vinylidene Fluoride: Phase Equilibrium Properties”, Fifth International Symposium on Supercritical Fluids (ISSF 2000), Atlanta, GA, April 10, 2000 (poster).

 

Charpentier, P. A., DeSimone, J. M. and Roberts, G. W., “Continuous Precipitation Polymerization of Vinylidene Fluoride”, Fifth International Symposium on Supercritical Fluids (ISSF 2000), Atlanta, GA, April 10, 2000 (poster).

 

February 5, 2000 - ACS/EPA Green Chemistry Workshop, Washington, D.C.  Scott Ragan, NSF STC Outreach Coordinator, invited participant.

March 13, 2000 - Expanding Your Horizons, an outreach conference for 500 middle school girls, NC State University, Raleigh, NC.  “Polymers”, presented by Darlene Taylor, Sarah Folk, Jennifer Polley, and Stephanie Crette, graduate students from UNC-CH.  “Engineering a Better World”, presented by Karen Kennedy and Teri Walker, graduate students from NC State University.

 

June 16, 2000 - Imhotep Academy of Physical and Mathematical Sciences at NC State, an academic camp for 50 minority and female middle school students, NC State University, Raleigh, NC.  “Using CO2 in Science”, presented by Scott Ragan, NSF STC Outreach Coordinator.

 

June 21, 2000 - The Pre-College Environmental Technology and Waste Management Workshop, for 100 high school minority students, sponsored by The Waste Management Institute at NC A&T State University, Greensboro, NC.  “Environmental and Waste Management Issues”, presented by Dr. Godfrey Uzochukwu from NC A&T.  “The NSF Science and Technology Center”, presented by Dr. Darlene Taylor from UNC-CH.  “Using CO2 in Our Everyday Lives”, presented by Scott Ragan, NSF STC Outreach Coordinator.  “Environmentally Responsible Solvents and Processes – Role of Carbon Dioxide”, presented by Dr. Kenneth Roberts from NC A&T.

 

Meeks, F.T., Hall, A., Saunders, K.B., Roberts, K.L., and White,G.L.,"Effect of Pressure and Contaminants on Surfactant/Supercritical Fluid Mixtures for Metal Substrate Cleaning", North Carolina SOARS Undergraduate Research Conference, November 12, 1999, Winston-Salem, NC.

 

Hall, A., Meeks, F.T., Saunders, K.B., Roberts, K.L., and White, G.L., "Surfactant/ Supercritical Fluid Reverse Micelle Mixtures for Advanced Cleaning Applications", National Society of Black Engineers Regional Conference, February 19, 2000, University Park, PA.

 

Roberts, K.L., Spence, T.S., Forbes, J.E., Pritchard, V.E., Saunders, K.B. and White, G.L., "Effect of Surfactant Type on the Cleaning of Metallic Substrates by Surfactant/Supercritical Fluid Mixtures", 5th International Symposium for Supercritical Fluids, April 10, 2000, Atlanta, GA.

 

March 2000, Annual APS meeting, Minneapolis, MN, Dynamics of Solutions of Associating Polymers. (Rubenstein)

 

J. R. Royer, Y. J. Gay, J. M. DeSimone, S. A. Khan; “Rheological Devices for Measurement of Polymeric Melts with Dissolved Supercritical Carbon Dioxide Under High-Pressure;” International Symposium on Supercritical Fluids; Atlanta, GA; April 2000.

 

J. R. Royer, J. M. DeSimone, S. A. Khan, “Development of High Pressure Rheological Devices and Measurement of Rheological Properties of CO2 Swollen Polymer Melts;” Richard Gilbert Symposium; NC ACS Polymer Discussion Group, Raleigh, NC; May 2000.

 

J. R. Royer, J. M. DeSimone, S. A. Khan, “Carbon Dioxide-Induced Plasticization of Polymer Melts: Rheology and Rheometer Design;” 4th Annual Green Chemistry and Engineering Conference:  National Academy of Sciences, Washington, D.C.; June 27-29, 2000.

 

R. G Carbonell, “Polymer Coatings from Liquid CO2”, ACS Regional Meeting, Cincinnati, OH, May 17-19, 2000

 

R. G. Carbonell, “The CO2 Technology Platform”, Department of Chemical Engineering, University of Ljubljana, Slovenia, June 19, 2000

 

Y. Chernyak, J. Edwards, R. Gould, R. Franklin, R. G. and Carbonell , “Materials processing by RESS”, Invited talk, Virginia Commonwealth University, Richmond, VA, June 1999

 

Y. Chernyak, J. Edwards, R. Gould, R. Franklin, R. G. and Carbonell, “Coatings from liquid and supercritical carbon dioxide”, American Vacuum Society 46th Int. Sypm., Seattle, WA, Oct. 1999

Y. Chernyak, J. Edwards, R. Gould, R. Franklin, R. G. and Carbonell, “Delivery of perfluoropolyether coatings from homogeneous solution in CO2 by the rapid expansion of supercritical solution (RESS) process”, AICHE Meeting, Dallas, TX, November 1999

 

Y. Chernyak, J. Edwards, R. Gould, R. Franklin, R. G. and Carbonell, “Delivery of perfluoropolyether coatings from homogeneous solution in CO2 by the rapid expansion of supercritical solution (RESS) process”, 5th Int. Symp. on Supercritical Fluids, Atlanta, GA, April 2000

 

E. Hoggan, D. Flowers, J. M. DeSimone, and R. G. Carbonell, “Spin coating using liquid and supercritical carbon dioxide”; The 5th International Symposium on Supercritical Fluids; Atlanta, Georgia, USA, April 8-12, 2000

 

E. Hoggan, D. Flowers, J. M. DeSimone, and R. G. Carbonell, “Spin coating and photolithography  using liquid and supercritical carbon dioxide”; 1999 AIChE Annual Meeting; Dallas, Texas; October 31 - November 5, 1999

 

E. Hoggan, D. Flowers, J. M. DeSimone, and R. G. Carbonell, “Spin coating and photolithography using liquid and supercritical carbon dioxide;  Supercritical Fluids in Materials Processing and Synthesis September 26- October 1, 1999; Davos, Switzerland

 

B. Novick, J. M. DeSimone, and R. G. Carbonell, “Free Meniscus Coatings from Liquid Carbon Dioxide”; The 5th International Symposium on Supercritical Fluids; Atlanta, Georgia, USA, April 8-12, 2000

 

B. Novick, J. M. DeSimone, and R. G. Carbonell, Polymeric Thin Film Coatings from Liquid Carbon Dioxide; 1999 AIChE Annual Meeting; Dallas, Texas; October 31st - November 5th, 1999

 

B. Novick, J. M. DeSimone, and R. G. Carbonell, Lubricant Coating in Liquid Carbon Dioxide;  Supercritical Fluids in Materials Processing and Synthesis September 26th - October 1st, 1999; Davos, Switzerland

 

E. I. Baucom, “National Science Foundation Science and Technology Center for Environmentally Responsible Solvents and Processes” and “Potential Energy Savings with CO2-Based Processes”, Department of Energy Workshop on Alternative Media, Conditions and Raw Materials, Corpus Christi, TX, February 23-25, 2000.

 

Gray, D.O. “Predicting and Enhancing Industrial Benefits from Cooperative Research: An Evolving Program of Research.” Paper presented at the Triple Helix International Conference, Rio de Janeiro, Brazil. April 2000.

 

Roberts, G.W.; Goodner, M.D.; Kiserow, D.J.; DeSimone, J.M.; Gross, S.M.; “Solid-State Polymerization of Polycarbonate Facilitated by Supercritical Carbon Dioxide”, AIChE Annual Meeting, Dallas, TX, October 31-November 5, 1999 (poster).       

 

Roberts, G.W.; Goodner, M.D.; Kiserow, D.J.; DeSimone, J.M.; Gross, S.M.; “Experimental and Modeling Studies of the Solvent-Induced Crystallization of Polycarbonate by Supercritical Carbon Dioxide”, AIChE Annual Meeting, Dallas, TX, October 31-November 5, 1999.

 

Goodner, M.D.; Gross, S.M.; DeSimone, J.M.; Roberts, G.W.; Kiserow, D.J.; “Modeling and Experimental Studies of the Solid-State Polymerization of Polycarbonate Facilitated by Supercritical Carbon Dioxide”, 217th ACS National Meeting, Anaheim, CA, March 21-25, 1999; Polymer Preprints, 40, No. 1, 97 (1999) (poster)

 

Goodner, M.D.; Gross, S.M.; DeSimone, J.M.; Roberts, G.W.; Kiserow, D.J.; “Broadening of Molecular Weight Distribution in Solid State Polymerization due to Condensate Diffusion”, accepted for publication in Jnl. App. Sci. AICHG meeting in Dallas.

 

Sonnenwald, D.H. “Collaboration across boundaries: Benefits, challenges and future directions. Southeast Affiliate of the International Association of Aquatic and Marine Science Librarians and Information Centers (SAIL) 2000 Meeting”. Environmental Protection Agency, Research Triangle Park, NC.

 

Sonnenwald, D.H. “Collaborative research within and across institutional boundaries.” Scholarly Productivity Workshop, Quality Education for Minorities Network. North Carolina Central University. 1999

 

Sonnenwald, D.H.  “An example from a study of lower socio-economic students’ information seeking behavior.”  Presentation at the Information Seeking in Context 2000 Conference.

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Patents:

 

Process in carbon dioxide for the preparation of polymers containing reactive isocyanate functionality, OTD #00-73.  DeSimone, J. M.

 

A process for the high-temperature chiral resolution of NaproxenÔ esters in aqueous,

semi-aqueous, and nonaqueous environments. Filed April, 2000. Sehgal, A.C., and  R.M. Kelly

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